위험물기능사 시험을 준비하는 수험생들을 위한 교재이다. 한국산업인력공단의 위험물기능사 필기 출제 기준에 맞추어 각 과목별로 정리하였으며 2016년까지의 출제문제를 분석하여 각 과목 세부 단원별 핵심이론정리와 예상문제를 수록하였다. 각 세부 단원별 이론 내용을 학습한 후 관련 예상문제를 곧바로 학습할 수 있도록 하였고, 예상문제 중에서 과년도에 변형되어 출제된 문제를 함께 수록하였다.

제1편 화재예방과 소화방법

제1장 화학의 이해
1-1 원소 주기율표 ·······································14
1. 원소의 주기율 ···································14
2. 화학 기호 ··········································14
3. 원자량, 분자량, 화학식량 ················15
1-2 물질의 상태와 화학적 성질 ·················18
1. 물질의 상태 ······································18
2. 열 ······················································19
1-3 기체의 상태 변화 ··································21
1. 보일-샤를의 법칙 ····························21
2. 이상기체 상태 방정식 ······················22
3. 비중, 밀도, 비체적 ··························23


제2장 연소 및 폭발
2-1 연소 이론 ···············································27
1. 연소(燃燒) ·········································27
2. 인화점 및 발화점 ·····························30
3. 연소범위 및 위험도 ··························33
4. 연소의 분류 ······································34
5. 자연발화 ···········································38
6. 정전기 제거설비 설치 ······················39
2-2 폭발의 종류 및 특성 ····························40
1. 폭발 ··················································40
2. 폭굉 ··················································41
3. BLEVE와 증기운 폭발 ····················42
2-3 화재의 분류 및 특성 ····························43
1. 화재의 정의 ······································43
2. 화재의 분류 및 특성 ························43
3. 화재 현상 ··········································46


제3장 소화 이론
3-1 소화 방법 ···············································48
1. 소화 ··················································48
2. 소화 방법의 종류 ·····························48
3-2 소화 약제 ···············································50
1. 소화약제의 종류 및 특징 ·················50
2. 소화약제별 소화효과 ························61


제4장 소화기 및 사용법
4-1 소화기의 종류 및 특성 ·························63
1. 포말(泡沫：foam) 소화기 ················63
2. 분말 소화기(드라이케미컬) ··············64
3. 할로겐 화합물 소화기 ······················65
4. 이산화탄소(CO2；탄산가스)
소화기 ···············································67
5. 강화액 소화기 ···································68
6. 산 ? 알칼리 소화기 ·····························68
7. 간이 소화제 ······································68
4-2 화재 종류 및 소화기 사용법 ···············71
1. 화재 종류 및 적응 소화기 ···············71
2. 소화기 사용 및 관리 ························71


제5장 위험물 화재
5-1 화재예방 및 소화방법 ··························73
1. 제1류 위험물 ····································73
2. 제2류 위험물 ····································73
3. 제3류 위험물 ····································74
4. 제4류 위험물 ···································74
5. 제5류 위험물 ····································75
6. 제6류 위험물 ····································75
5-2 화재 발생 시 조치 방법 ·······················75
1. 제1류 위험물 ····································75
2. 제2류 위험물 ····································76
3. 제3류 위험물 ····································76
4. 제4류 위험물 ····································76
5. 제5류 위험물 ····································77
6. 제6류 위험물 ····································77


제2편 위험물의 종류 및 성질

제1장 위험물의 종류
1-1 위험물 용어 ···········································82
1. 위험물 안전관리법 총칙 ···················82
2. 위험물 및 지정수량 ··························83
1-2 반응 생성물 ···········································91
1. 가연성 가스를 발생하는 위험물 ······91
2. 유독한 가스를 발생하는 위험물 ······93


제2장 제1류 위험물
2-1 제1류 위험물의 종류 ····························95
1. 제1류 위험물의 종류 및 지정수량 ··95
2. 제1류 위험물의 공통적인 성질 ········96
3. 저장 및 취급 시 주의사항 ···············96
4. 소화 방법 ··········································96
2-2 제1류 위험물의 성질 및 위험성 ··········98
1. 아염소산염류 ····································98
2. 염소산염류 ········································99
3. 과염소산염류 ··································101
4. 무기과산화물 ··································105
5. 브롬산염류 ······································111
6. 질산염류 ·········································113
7. 요오드(옥소)산염류 ·························116
8. 과망간산염류 ··································117
9. 중크롬산염류 ··································118


제3장 제2류 위험물
3-1 제2류 위험물의 종류 ··························120
1. 제2류 위험물의 종류 및 지정수량 ··········120
2. 제2류 위험물의 공통적인 성질 ······121
3. 저장 및 취급 시 주의사항 ·············121
4. 소화 방법 ·······································121
3-2 제2류 위험물의 성질 및 위험성 ·······123
1. 황화린(황화인) ································123
2. 적린 ················································125
3. 유황 ················································127
4. 철분 ················································129
5. 금속분 ·············································130
6. 마그네슘 ·········································133
7. 인화성 고체 ····································135


제4장 제3류 위험물
4-1 제3류 위험물의 종류 ··························136
1. 제3류 위험물의 종류 및
지정수량 ·········································136
2. 제3류 위험물의 공통적인 성질 ······137
3. 저장 및 취급 시 주의사항 ·············137
4. 소화 방법 ·······································137
4-2 제3류 위험물의 성질 및 위험성 ·······138
1. 칼륨 ················································138
2. 나트륨 ·············································140
3. 알킬알루미늄 ··································142
4. 알킬리튬 ·········································145
5. 황린 ················································145
6. 알칼리금속 및 알칼리토금속 ··········148
7. 유기금속 화합물 ·····························150
8. 금속의 수소화물 ·····························150
9. 금속의 인화물 ································152
10. 칼슘 또는 알루미늄의 탄화물 ······153


제5장 제4류 위험물
5-1 제4류 위험물의 종류 ··························157
1. 제4류 위험물의 종류 및 지정수량···157
2. 제4류 위험물의 성상에 의한
품명 분류 ·······································157
3. 제4류 위험물의 공통적인 성질 ······158
4. 저장 및 취급 시 주의사항 ·············158
5. 소화 방법 ·······································159
5-2 제4류 위험물의 성질 및 위험성 ·······161
1. 특수인하물 ······································161
2. 제1석유류 ·······································167
3. 알코올류 ·········································176
4. 제2석유류 ·······································180
5. 제3석유류 ·······································186
6. 제4석유류 ·······································189
7. 동식물유류 ······································189


제6장 제5류 위험물
6-1 제5류 위험물의 종류 ··························192
1. 제5류 위험물의 종류 및 지정수량···192
2. 제5류 위험물의 공통적인 성질 ······193
3. 저장 및 취급 시 주의사항 ·············193
4. 소화 방법 ·······································193
6-2 제5류 위험물의 성질 및 위험성 ·······194
1. 유기과산화물 ··································194
2. 질산에스테르류 ·······························198
3. 니트로 화합물 ································205
4. 니트로소 화합물 ·····························209
5. 아조 화합물 ····································209
6. 디아조 화합물 ································210
7. 히드라진 유도 ································210
8. 히드록실아민(NH2OH) ···················210
9. 히드록실아민염류 ···························210


제7장 제6류 위험물
7-1 제6류 위험물의 종류 ··························212
1. 제6류 위험물의 종류 및
지정수량 ·········································212
2. 제6류 위험물의 공통적인 성질 ······212
3. 저장 및 취급 시 주의사항 ·············213
7-2 제6류 위험물의 성질 및 위험성 ·······214
1. 과염소산(HClO4) ····························214
2. 과산화수소(H2O2) ··························214
3. 질산(HNO3) ···································215


제3편 위험물 안전관리 및 기술기준

제1장 소화설비 설치기준
1-1 소방시설의 종류 및 특성 ···················222
1. 소방시설의 종류 ·····························222
2. 소화설비 설치의 구분 ····················222
3. 소화설비 특성 ································223
1-2 위험물 제조소등의 소화설비 기준 ····226
1. 소화설비의 기준 ·····························226
2. 옥내소화전 설비 ·····························226
3. 옥외소화전 설비 ·····························229
4. 스프링클러 설비 ·····························231
5. 물분무 소화설비 ·····························233
6. 포소화설비 ······································235
7. 불활성가스 소화설비 ······················236
8. 기타 소화설비 ································238


제2장 소화설비 설치 및 운영
2-1 소화설비 설치 ·····································241
1. 소화난이도등급 Ⅰ의 제조소등 및
소화설비 ·········································241
2. 소화난이도등급 Ⅱ의 제조소등 및
소화설비 ·········································244
3. 소화난이도등급 Ⅲ의 제조소등 및
소화설비 ·········································245
2-2 위험물 성질에 따른 소화설비 기준 ··250
1. 소화설비의 적응성 ·························250
2. 소요단위 및 능력단위 산정법 ········255


제3장 경보 및 피난설비 설치기준
3-1 경보 및 피난설비 종류 ······················261
1. 경보설비 ·········································261
2. 피난구조설비 ··································261
3. 소화용수설비, 소화활동설비 ··········261
3-2 경보설비 설치 기준 ····························262
1. 경보설비 ·········································262
2. 자동화재 탐지설비 설치기준 ··········263
3-3 피난설비의 설치 기준 ························268
1. 피난설비 ·········································268


제4장 위험물 저장 ? 취급 ? 운반 ? 운송기준
4-1 위험물의 저장 및 취급 장소 ·············270
1. 위험물을 저장 및 취급하기 위한
장소 ···············································270
4-2 위험물의 저장, 취급기준 ···················273
1. 위험물 저장 및 취급 ······················273
2. 제조소등에서의 위험물의 저장 및
취급에 관한 기준 ···························274
3. 취급의 기준 ····································276
4-3 위험물의 운반 기준 ····························280
1. 운반용기 ·········································280
2. 적재방법 ·········································280
3. 운반용기의 외부 표시사항 ·············286
4. 위험물의 위험등급 ·························288
5. 운반용기의 최대용적 또는 중량 ····292
6. 운반방법 ·········································294
4-4 위험물의 운송 기준 ····························295
1. 위험물의 운송 ································295
2. 운송책임자의 감독 또는
지원 방법 ·······································295
3. 이동탱크 저장소에 의한 위험물
운송 시 준수사항 ···························296


제5장 제조소등의 위치 ? 구조 ? 설비기준
5-1 제조소 기준 ·········································299
1. 위치 기준 ·······································299
2. 구조 및 설비 기준 ·························301
5-2 옥내저장소 기준 ··································311
1. 위치 기준 ·······································311
2. 구조 및 설비 기준 ·························312
5-3 옥외탱크 저장소 기준 ························317
1. 위치 기준 ·······································317
2. 구조 및 설비 기준 ·························318
5-4 옥내탱크 저장소 기준 ························327
5-5 지하탱크 저장소 기준 ························329
5-6 간이탱크 저장소 기준 ························333
5-7 이동탱크 저장소 기준 ························335
1. 상치 장소 기준 ·······························335
2. 이동저장탱크의 구조 ······················335
5-8 옥외 저장소 기준 ································338
5-9 암반탱크 저장소 기준 ························340
5-10 주유 취급소 기준 ······························342
5-11 판매 취급소 기준 ·······························348
1. 제1종 판매취급소 기준 ··················348
2. 제2종 판매취급소 기준 ··················348
5-12 이송 취급소 기준 ······························350
5-13 탱크 용량 계산 및 수압시험 ············353
1. 탱크 용량 계산 ·······························353
2. 탱크의 수압시험(변형시험) ············354


제4편 위험물 안전관리법

제1장 제조소등 설치 및 후속절차
1-1 제조소등 허가 ·····································360
1. 위험물시설의 설치 및 변경 허가 ··360
2. 제조소등의 완공검사 ······················361
1-2 제조소등의 지위승계 및 용도폐지 ····364
1. 제조소등 설치자의 지위승계 ··········364
2. 제조소등의 용도 폐지 ····················365
1-3 탱크안전 성능검사 ······························366
1. 탱크안전 성능검사 ·························366
2. 탱크시험자 ······································367


제2장 행정감독 및 처분
2-1 행정감독 ···············································369
1. 과징금 ·············································369
2. 감독 및 조치명령 ···························369
3. 각종 행정 명령 ·······························370
4. 벌금 및 과태료 ·······························370
2-2 행정처분 ···············································373
1. 일반기준 ·········································373
2. 행정처분 ·········································373


제3장 안전관리 사항
3-1 위험물시설의 안전관리 ·······················376
1. 위험물시설의 유지 ? 관리 ················376
2. 위험물 안전관리자 ·························376
3. 안전교육 ·········································378
3-2 예방규정 ···············································381
1. 관계인이 예방규정을 정하여야 하는
제조소등 ·········································381
2. 예방규정의 작성 등 ························381
3-3 정기점검 및 검사 ································384
1. 정기점검 및 정기검사 ····················384
2. 정기검사 ·········································384
3-4 자체소방대 ···········································386
1. 자체소방대 ······································386
2. 자체소방대를 설치하여야 하는
사업소 ·············································386
3. 자체소방대의 설치 제외 대상인
일반취급소 ······································387


부록 Ⅰ 과년도 출제문제
· 2013년도 출제문제 90
· 2014년도 출제문제 448
· 2015년도 출제문제 507
· 2016년도 출제문제 567


부록 Ⅱ CBT 모의고사
제1회 CBT 모의고사 612
제2회 CBT 모의고사 618
제3회 CBT 모의고사 625
제4회 CBT 모의고사 632
·모의고사 정답 및 해설 639

서상희

이 책은 저자가 수년간의 강의경험과 관련 자료를 준비하여 CBT 대비 위험물기능사 필기시험을 준비하는 수험생들의 실력 배양 및 합격에 도움이 되고자 다음 사항에 중점을 두고 구성하였다.


첫째, 한국산업인력공단의 위험물기능사 필기 출제 기준에 맞추어 각 과목별로 정리하였다.

둘째, 2016년까지의 출제문제를 분석하여 각 과목 세부 단원별 핵심이론정리와 예상문제를 수록하여 CBT 필기시험에 대비할 수 있도록 하였다.

셋째, 각 세부 단원별 이론 내용을 학습한 후 관련 예 상문제를 곧바로 학습할 수 있도록 하였고, 예상문 제 중에서 과년도에 변형되어 출제된 문제를 함께 수록하여 학습능률 증대와 함께 변형된 문제에 대 비할 수 있도록 하였다.

넷째, 2012년부터 2016년 제4회까지 시행되었던 5년 간의 필기문제를 자세한 해설과 함께 수록하였다.

다섯째, CBT 대비 모의고사를 자세한 해설과 함께 수록하여 CBT 필기시험 전에 실력을 점검·확인 할 수
있도록 하였다.

여섯째, 저자가 직접 인터넷 카페를 개설, 관리하여 온라인상으로 질문 및 답변과 함께 시험정보를 공 유할 수 있는 공간을 마련하였다.